Systemd config files need absolute paths.

LimitCore was ment to be LimitCORE

Oct 14 07:28:04 spaceman systemd[1]: [/etc/systemd/system/mariadb.service.d/migrated-from-my.cnf-settings.conf:7] Unknown lvalue 'LimitCore' in section 'Service'
Oct 14 07:28:04 spaceman systemd[1]: [/etc/systemd/system/mariadb.service.d/migrated-from-my.cnf-settings.conf:9] Executable path is not absolute, ignoring: sync
Oct 14 07:28:04 spaceman systemd[1]: [/etc/systemd/system/mariadb.service.d/migrated-from-my.cnf-settings.conf:10] Executable path is not absolute, ignoring: sysctl -q -w vm.drop_caches=3